Dear Fengzhou,
It is true that ST25DV does not embed a storage capacitor. The energy harvesting output is unregulated and unfiltered and its value is directly dependent on how much energy is received by the ST25DV.
So, at output of the ST25DV energy harvesting, depending on your application, you may want to add some filtering and a tank capacitor.
If you need clean voltage, you need to filter 27.12MHz (twice the 13.56MHz from the RF field since it is rectified).
The tank capacitor is used to limit voltage drop in case of peak of current surge from the powered device. Its value really depends on the current variation from the connected device.
You can find curves of what current the ST25DV can deliver versus energy harvesting voltage in the application note AN4913 https://www.st.com/resource/en/application_note/an4913-energy-harvesting-delivery-impact-on-st25dvi2c-series-behaviour-during-rf-communication-stmicroelectronics.pdf
For a given RF field power, the ST25DV can deliver a fixed power. So, the more current you draw, the less voltage you are given.
To calculate your capacitor, you should know the peak current consumption of your device, and choose it so that current drawn seen by the ST25DV upstream the capacitor is kept below the limit of your minimum possible voltage.
Best regards.