@Haystak wrote:
I opened the UM1725 file but couldn't find the description for the pins just found the description for Arduino connectors
Table 30, as you showed, describes the Morpho connectors - that's the outer double rows of pins.
For the Arduino pins, see Table 18:

These tell you which of the microcontroller's pins is connected to each pin on those connectors.
Not sure what further "description" of the pins you're looking for?
The names of the pins in these tables are the same names used in the datasheet table you showed initially:

As @STTwo-32 said, the datasheet lists pins for all possible package variants; the ones you highlighted are only available on the UFBGA100 package (Red) - they are not available on the LQFP64 package (Blue) used on the Nucleo board.
EDIT: highlight the different packages
EIDT 2:
In the case of the pin highlighted in yellow:
- The name of the pin is "PE6" - this is the name that the Nucleo tables refer to
- The position of the pin on the UFBGA100 package is "D2"
- The position of the pin on the LQFP100 package is "5"
- The pin is not present on any of the other packages - including the LQFP64 package used on the Nucleo board.
- The pin named "PE6" can be configured for one of the Alternate Functions TIM21_CH2 or TIM3_CH4, or the Additional Functions RTC_TAMP3 or WKUP3