The DISCOVERY kits are intended to be able to evaluate as many functions of the target STM32 as possible. For this purpose, many peripherals are already connected, including external components, e.g. sensors.
But unfortunately the number of pins of each STM32 is limited, which is why it is not possible to make all imaginable functions available in the DISCOVERY at the same time. In order to actually be able to test all functions, either an EVALUATION board is required, or a customer-specific design.
Good luck!
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/Peter