Solved
Pristine STM32L431 PA6 turned to hard output
When switching on a new, unprogrammed STM32L431, PA6 turns hard to output high.
This is SPI1 MOSI.
AN2606 should say this out aloud.
I know the 'G0 have this too, and AN2606 says this for them, although quite quietly and confusingly in a footnote.
JW

