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Peter BENSCH
Technical Moderator
May 30, 2024

Welcome @columbine84, to the community!

this reason is actually also stated in the AN5571 you referenced:

[page 2] The reference junction is at the reference temperature and, in order to ensure a good stability, this reference junction is generally measured by a thermistor.
...
[page 3] The output of the thermopile can vary depending on the ambient temperature. A thermistor is generally used to compensate this possible drift.

Hope that answers your question?

Regards
/Peter