The do interfere a little bit. If you place them directly at each other, or in the same direction looking at a particularly reflective object you will find some interference.
but if they are close and pointed at different directions you should be just fine. A little light at the edges of one sensor might slightly distort the one edge of the one next to it, but the effect will be hardly noticeable.
if you really are worried about it, start them at slightly different times.
Start the even ones, then the odd ones, then try to keep up with all that I/O. Extra points if you can put them on separate I2C busses. But kicking them off at slightly different times, they cannot be in sync. And that will work to your advantage.
I'm not quite sure I understand your other question. The sensors do a Radial-to-Perpendicular calculation. So if you put then perpendicular to a flat wall, all the zones will return the same distance. (Even though the light travels farther at the edges.)
So you can develop a point cloud using this data. There is some code on this community page:
VL53L5CX Multi-Zone Sensor get x,y,z of points rel... - STMicroelectronics Community
(The L5 and L8 have the same chip geometry, so don't worry that it says "L5". It still works.